After watching several videos on #retrobrighting techniques, I started a couple of small-scale experiments to see if my setup works.
This year's Christmas decorations will shine in UV light!
If you followed my A3000 restoration threads, you can easily guess which yellowed plastic I need to retrobright
https://mstdn.io/@codewiz/113586277421694238
This cheap PC keyboard will go first to test the effectiveness of my #retrobrighting process.
The very first step consists in a bath in dish soap and hot water. This should prevent grease and other dirt from blocking the UV light and the ozone.
While I was at it, I also threw in the PCB, just to see if my soap is safe for electronics.
Then I rinsed everything with fresh water and wiped with 70% isopropyl, which didn't seem to disturb the key engravings.
Many #retrobrighting videos dip the plastic to be treated in concentrated hydrogen peroxide, or coat it with hair bleaching cream, which may contain other chemicals.
But 12% peroxide is kinda expensive, and I couldn't find any in nearby stores. The fastest delivery I could find wouldn't arrive in time for Santa to admire my first retrobrighted keyboard.
So I decided to try an alternative: sodium carbonate. Pure and natural since 1874... and dirt cheap at $0.10 per ounce!
I'm no chemist. Until yesterday, I didn't even realize that washing soda isn't the same of baking soda (sodium *BI*carbonate).
But I suspect what was actually needed was sodium *PER*carbonate!
https://en.wikipedia.org/wiki/Sodium_percarbonate
Wikipedia confirms that, in water, percarbonate decomposes into hydrogen peroxide. Which is why it works the same for #retrobrighting.
But I don't have any percarbonate at home, and it won't arrive before Dec 29 either.
Moreover, how much would I need to get the equivalent of 12% peroxide? Now I regret not paying enough attention in #chemistry classes!
Before realizing that sodium percarbonate was actually what I was supposed to use, I started a small AB-test in my UV chamber using plenty of sodium carbonate.
After spending about 12 hours dipped in the solution, the '+' key (treatment) is visibly less yellow than the '-' key (control).
Despite using the wrong #chemistry, my first #retrobrighting experiment didn't completely fail. Can anyone explain this surprising result?
I also bought a Sterilite storage box large enough for the A3000 keyboard. I believe it's made of polypropylene or polyethylene, which shouldn't block UV too much, but since my led strip is IP65, I figured I can just hang them on the inside of the lid.
While waiting for one gallon of 12% hydrogen peroxide from Home Depot, I started another #retrobrighting experiment with concentrated sodium carbonate solution, just on a larger scale than the minus key.
While the #chemistry is the same, the conditions are quite different:
- I had to weight the plastic to keep it from floating: will the covered areas look different?
- The same UV light source is being diffused in a much larger environment
- 5W of light won't keep this larger reactor warm, so I moved my electric room heater next to it
- This cheap box doesn't have a gasket all around the lid. Will it quickly vent out the radicals produced by peroxide decomposition in UV?
My second #retrobrighting experiment with sodium carbonate for 24h ended with a slightly paler PC keyboard.
The result is very uneven and the engravings look bleached. I'd call it a failure: don't bathe your vintage plastic in sodium carbonate!
The two controls on the left have been kept outside the box (backspace) and inside, but suspended above the liquid (equals/plus).
Meanwhile, the 12% peroxide arrived, and I poured the entire 1 gal bottle in my #retrobrighting reactor for another 24h session with that poor PC keyboard.
Notice the =/+ key sitting on top of a plastic weight to compare the effectiveness of the reaction in air.
While hydrogen peroxide (H2O2) is commonly used to disinfect wounds and even for oral rinsing, at 12% concentration it must be handled with gloves.
I touched the wet plastic with my bare fingers, and after a few seconds they were stinging, and the skin was already partially corroded.
I guess that's why you can't purchase peroxide at higher concentrations from retail stores in the US.
@codewiz I think the other reason is it's used for making bombs.
And how many gallons of peroxide can I buy online before they raid my house, find this weird box glowing in purple light and go: "aha! take him away!", without letting me finish to explain retrobrighting and vintage computing?